Controlling Orthogonal Self-Assembly through Cis-Trans Isomerization of a Non-Covalent Palladium Complex Dimer

Crosbi ID246271
Bib IRB ID916168
Year2018
StatusObjavljeno
Typeprilog u časopisu
Subtypeizvorni znanstveni rad
AuthorsKokan, Zoran ; Kovačević, Borislav ; Štefanić, Zoran ; Tzvetkova, Pavleta ; Kirin, Srećko I.
JournalChemical communications
Volume54
Issue17
Pagesstr. 2094-2097
DOI10.1039/c7cc09537f
ISSN1359-7345
EISSN1364-548X
Titles

en original Controlling Orthogonal Self-Assembly through Cis-Trans Isomerization of a Non-Covalent Palladium Complex Dimer

Abstracts
en original

The trans-configured square-planar complex of dichloropalladium and chiral monodentate phosphine ligands forms self-complementary dimers through 16 hydrogen bonded amides and π- π stacking in chlorinated solvents. The self- assembly is controled by cis-trans isomerisation of the metal center, where trans- configuration governs the dimer formation.

Keywords

en original dichloropalladium ; chiral ; self-assembly

Authors
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Citations
Kokan, Zoran ; Kovačević, Borislav ; Štefanić, Zoran ; Tzvetkova, Pavleta ; Kirin, Srećko I.
Controlling Orthogonal Self-Assembly through Cis-Trans Isomerization of a Non-Covalent Palladium Complex Dimer // Chemical communications, 54 (2018), 17; 2094-2097. doi: 10.1039/C7CC09537F
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